ABSTRACT
<p><b>OBJECTIVE</b>To establish a method for determination of a variety of acid gas in the workplace air by Ion Chromatography. (hydrofluoric acid, hydrogen chloride or hydrochloric acid, sulfur anhydride or sulfuric acid, phosphoric acid, oxalic acid).</p><p><b>METHOD</b>The sample in workplace air was collected by the porous glass plate absorption tube containing 5 ml leacheate. (Sulfuric acid fog, phosphoric acid aerosol microporous membrane after collection, eluted with 5 ml of eluent.) To separated by AS14+AG14 chromatography column, by carbonate (2.0+1.0) mmol/L (Na(2)CO(3)-NaHCO(3)) as eluent, flow rate of 1 ml/min, then analyzed by electrical conductivity detector. The retain time was used for qualitative and the peak area was used for quantitation.</p><p><b>RESULTS</b>The each ion of a variety of acid gas in the air of workplace were excellent in carbonate eluent separation. The linear range of working curve of 0∼20 mg/L. The correlation coefficient r>0.999; lower detection limit of 3.6∼115 µg/L; quantitative limit of 0.012∼0.53 mg/L; acquisition of 15L air were measured, the minimum detection concentration is 0.004 0∼0.13 mg/m(3). The recovery rate is 99.7%∼101.1%. In the sample without mutual interference ions. Samples stored at room temperature for 7 days.</p><p><b>CONCLUSION</b>The same analysis method, the detection of various acidic gases in the air of workplace, simple operation, good separation effect, high sensitivity, high detection efficiency, easy popularization and application.</p>
Subject(s)
Acids, Noncarboxylic , Air , Air Pollutants, Occupational , Chromatography , Methods , Gases , Hydrochloric Acid , Hydrofluoric Acid , Ions , Limit of Detection , Phosphoric Acids , Sulfuric Acids , WorkplaceABSTRACT
O objetivo deste estudo foi avaliar a topograa da superfície das cerâmicas Noritake, IPS e.max e Cercon quando empregado o jateamento com óxido de alumínio ou o condicionamento com ácido uorídrico. Foram confeccionadas seis amostras de cada cerâmica (10mm x 10mm x 0,5mm), sendo divididas em três grupos: Grupo 1: sem tratamento de superfície (controle); Grupo 2: jateamento com óxido de alumínio de 50 µm; Grupo 3: ácido uorídrico a 10%. As amostras foram metalizadas e observadas em microscópio eletrônico de varredura. O ácido uorídrico a 10% aumentou a irregularidade supercial das cerâmicas Noritake e IPS e.max, mas não alterou a topograa supercial da cerâmica Cercon. O jateamento com óxido de alumínio aumentou a irregularidade supercial das cerâmicas Noritake, IPS e.max e Cercon. Concluiu-se que o ácido uorídrico foi efetivo somente para as cerâmicas Noritake e IPS e.max, e o jateamento foi efetivo para as três cerâmicas.
The purpose of this study was to evaluate the surface topography of Noritake, IPS e.max and Cercon ceramics after treatment with either airborne aluminum oxide particle abrasion or hydrouoric acid etching. Six specimens of each ceramic (10mm x 10mm x 0,5mm) were fabricated and randomly divided into three groups: Group 1: without surface treatment (control); Group 2: airborne particle abrasion with 50-µm aluminum oxide; Group 3: 10% hydrouoric acid etching. The specimens were gold coated and examined using scanning electron microscopy. The 10% hydrouoric acid increased the surface irregularities of Noritake and IPS e.max ceramics, but did not change the surface topography of Cercon ceramic. Airborne particle abrasion with aluminum oxide increased the surface irregularities of Noritake, IPS e.max and Cercon ceramics. It was concluded that hydrouoric acid was effective only for Noritake and IPS e.max ceramics, and airborne particle abrasion was effective for the three ceramics.